Binary coefficients such as binary diffusion coefficients, Henry coefficients.
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Binary coefficients describe the relations of a mixture of two components. Typical binary coefficients are Henry coefficients or binary molecular diffusion coefficients.
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| file | air_mesitylene.hh |
| | Binary coefficients for air and mesitylene.
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| file | air_xylene.hh |
| | Binary coefficients for air and xylene.
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| file | brine_co2.hh |
| | Binary coefficients for CO2 and brine.
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| file | fullermethod.hh |
| | Various relations for molecular diffusion coefficients.
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| file | h2o_air.hh |
| | Binary coefficients for water and air.
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| file | h2o_ch4.hh |
| | Binary coefficients for water and methane.
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| file | h2o_constant.hh |
| | Binary coefficients for water and a "constant" component.
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| file | h2o_heavyoil.hh |
| | Binary coefficients for water and heavy oil.
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| file | h2o_mesitylene.hh |
| | Binary coefficients for water and mesitylene.
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| file | h2o_n2.hh |
| | Binary coefficients for water and nitrogen.
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| file | h2o_o2.hh |
| | Binary coefficients for water and oxygen.
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| file | h2o_xylene.hh |
| | Binary coefficients for water and xylene.
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| file | henryiapws.hh |
| | The IAPWS formulation of Henry coefficients in water.
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| file | n2_o2.hh |
| | Binary coefficients for nitrogen and oxygen.
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| template<class Scalar > |
| Scalar | Dumux::BinaryCoeff::fullerMethod (const Scalar *M, const Scalar *SigmaNu, const Scalar temperature, const Scalar pressure) |
| | Estimate binary diffusion coefficients \(\mathrm{[m^2/s]}\) in gases according to the method by Fuller. More...
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| template<class Scalar > |
| Scalar | Dumux::henryIAPWS (Scalar E, Scalar F, Scalar G, Scalar H, Scalar temperature) |
| | The Henry constants in liquid water using the IAPWS 2004 formulation. More...
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◆ fullerMethod()
template<class Scalar >
| Scalar Dumux::BinaryCoeff::fullerMethod |
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const Scalar * |
M, |
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const Scalar * |
SigmaNu, |
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const Scalar |
temperature, |
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const Scalar |
pressure |
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) |
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inline |
- Parameters
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| M | molar masses \(\mathrm{[g/mol]}\) |
| SigmaNu | atomic diffusion volume |
| temperature | The temperature \(\mathrm{[K]}\) |
| pressure | phase pressure \(\mathrm{[Pa]}\) |
This function estimates the diffusion coefficients in binary gases using to the method proposed by Fuller. This method and is only valid at "low" pressures.
See: R. Reid, et al. (1987, pp. 587-588) [70]
◆ henryIAPWS()
template<class Scalar >
| Scalar Dumux::henryIAPWS |
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Scalar |
E, |
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Scalar |
F, |
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Scalar |
G, |
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Scalar |
H, |
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Scalar |
temperature |
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) |
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inline |
- Parameters
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| E | Correlation parameter |
| F | Correlation parameter |
| G | Correlation parameter |
| H | Correlation parameter |
| temperature | the temperature \(\mathrm{[K]}\) |
This function calculates \(\mathrm{K_D}\), see:
IAPWS: "Guideline on the Henry's Constant and Vapor-Liquid
Distribution Constant for Gases in H2O and D2O at High
Temperatures" Equation (5) [86]
Range of validity: T = {278.12 ; 636.46} approximations beyond this range are increasingly incorrect. However, close to the critical the values are more, again.
1.9.3