Binary Coefficients

Binary coefficients. More...

Description

Binary coefficients.

Binary coefficients describe the relations of a mixture of two components. Typical binary coefficients are Henry coefficients or binary molecular diffusion coefficients. So far, the programming interface for accessing binary coefficients has not been standardized in Dumux.

Files
file	air_mesitylene.hh
	Binary coefficients for air and mesitylene.
file	air_xylene.hh
	Binary coefficients for air and xylene.
file	brine_co2.hh
	Binary coefficients for CO2 and brine.
file	fullermethod.hh
	Various relations for molecular diffusion coefficients.
file	h2o_air.hh
	Binary coefficients for water and air.
file	h2o_ch4.hh
	Binary coefficients for water and methane.
file	h2o_constant.hh
	Binary coefficients for water and a "constant" component.
file	h2o_heavyoil.hh
	Binary coefficients for water and heavy oil.
file	h2o_mesitylene.hh
	Binary coefficients for water and mesitylene.
file	h2o_n2.hh
	Binary coefficients for water and nitrogen.
file	h2o_o2.hh
	Binary coefficients for water and oxygen.
file	h2o_xylene.hh
	Binary coefficients for water and xylene.
file	henryiapws.hh
	The IAPWS formulation of Henry coefficients in water.
file	n2_o2.hh
	Binary coefficients for nitrogen and oxygen.

Classes
class	Dumux::BinaryCoeff::Air_Mesitylene
	Binary coefficients for water and mesitylene. More...
class	Dumux::BinaryCoeff::Air_Xylene
	Binary coefficients for air and xylene. More...
class	Dumux::BinaryCoeff::Brine_CO2< Scalar, CO2Tables, verbose >
	Binary coefficients for brine and CO2. More...
class	Dumux::BinaryCoeff::H2O_Air
	Binary coefficients for water and air. More...
class	Dumux::BinaryCoeff::H2O_CH4
	Binary coefficients for water and methane. More...
class	Dumux::BinaryCoeff::H2O_Component< Scalar, Component >
	Binary coefficients for water and another component. More...
class	Dumux::BinaryCoeff::H2O_Component< Scalar, Components::Constant< id, Scalar > >
	Binary coefficients for water and a constant component. More...
class	Dumux::BinaryCoeff::H2O_HeavyOil
	Binary coefficients for water and heavy oil as in SAGD processes. More...
class	Dumux::BinaryCoeff::H2O_Mesitylene
	Binary coefficients for water and mesitylene. More...
class	Dumux::BinaryCoeff::H2O_N2
	Binary coefficients for water and nitrogen. More...
class	Dumux::BinaryCoeff::H2O_O2
	Binary coefficients for water and oxygen. More...
class	Dumux::BinaryCoeff::H2O_Xylene
	Binary coefficients for water and xylene. More...
class	Dumux::BinaryCoeff::N2_O2
	Binary coefficients for nitrogen and oxygen. More...

Functions
template<class Scalar >
Scalar	Dumux::BinaryCoeff::fullerMethod (const Scalar *M, const Scalar *SigmaNu, const Scalar temperature, const Scalar pressure)
	Estimate binary diffusion coefficients \(\mathrm{[m^2/s]}\) in gases according to the method by Fuller. More...
template<class Scalar >
Scalar	Dumux::henryIAPWS (Scalar E, Scalar F, Scalar G, Scalar H, Scalar temperature)
	The Henry constants in liquid water using the IAPWS 2004 formulation. More...

Function Documentation

fullerMethod()

template<class Scalar >

Scalar Dumux::BinaryCoeff::fullerMethod ( const Scalar *  M, const Scalar *  SigmaNu, const Scalar  temperature, const Scalar  pressure  )

inline

Estimate binary diffusion coefficients \(\mathrm{[m^2/s]}\) in gases according to the method by Fuller.

Parameters

M	molar masses \(\mathrm{[g/mol]}\)
SigmaNu	atomic diffusion volume
temperature	The temperature \(\mathrm{[K]}\)
pressure	phase pressure \(\mathrm{[Pa]}\)

This function estimates the diffusion coefficients in binary gases using to the method proposed by Fuller. This method and is only valid at "low" pressures.

See: R. Reid, et al. (1987, pp. 587-588) [59]

henryIAPWS()

template<class Scalar >

Scalar Dumux::henryIAPWS ( Scalar  E, Scalar  F, Scalar  G, Scalar  H, Scalar  temperature  )

inline

The Henry constants in liquid water using the IAPWS 2004 formulation.

Parameters

E	Correlation parameter
F	Correlation parameter
G	Correlation parameter
H	Correlation parameter
temperature	the temperature \(\mathrm{[K]}\)

This function calculates \(\mathrm{K_D}\), see:

IAPWS: "Guideline on the Henry's Constant and Vapor-Liquid Distribution Constant for Gases in H2O and D2O at High Temperatures" Equation (5) [74]

Range of validity: T = {278.12 ; 636.46} approximations beyond this range are increasingly incorrect. However, close to the critical the values are more, again.