region2.hh

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// -*- mode: C++; tab-width: 4; indent-tabs-mode: nil; c-basic-offset: 4 -*-
// vi: set et ts=4 sw=4 sts=4:
//
// SPDX-FileCopyrightInfo: Copyright © DuMux Project contributors, see AUTHORS.md in root folder
// SPDX-License-Identifier: GPL-3.0-or-later
//
 
#ifndef DUMUX_IAPWS_REGION2_HH
#define DUMUX_IAPWS_REGION2_HH
 
#include <cmath>
#include <iostream>
#include <dumux/common/exceptions.hh>
 
namespace Dumux {
namespace IAPWS {
 
template <class Scalar>
class Region2
{
public:
    static void checkValidityRange(Scalar temperature, Scalar pressure,
                                   const std::string& propertyName = "This property")
    {
        // actually this is:
        /* (273.15 <= temperature && temperature <= 623.15 && pressure <= vaporPressure(temperature)) ||
           (623.15 < temperature && temperature <= 863.15 && pressure <= auxPressure(temperature)) ||
           (863.15 < temperature && temperature <= 1073.15 && pressure < 100e6); */
        if ((temperature <= 623.15 && pressure <= 100e6) ||
            (temperature > 623.15 && temperature <= 1073.15 && pressure <= 16.532e6 ))
            return;
 
        DUNE_THROW(NumericalProblem,
                   propertyName << " of steam is only implemented for temperatures below 623.15K and "
                   "pressures below 100MPa. (T=" << temperature << ", p=" << pressure << ")");
    }
 
    static constexpr Scalar tau(Scalar temperature)
    { return 540.0 / temperature; }
 
    static constexpr Scalar dTau_dt(Scalar temperature)
    { return - 540.0 / (temperature*temperature); }
 
    static constexpr Scalar pi(Scalar pressure)
    { return pressure / 1e6; }
 
    static constexpr Scalar dPi_dp(Scalar pressure)
    { return 1.0 / 1e6; }
 
    static constexpr Scalar dp_dPi(Scalar pressure)
    { return 1e6; }
 
    static Scalar gamma(Scalar temperature, Scalar pressure)
    {
        Scalar tau = tau(temperature);   /* reduced temperature */
        Scalar pi = pi(pressure);    /* reduced pressure */
 
        Scalar result;
 
        // ideal gas part
        using std::pow;
        result = ln(pi);
        for (int i = 0; i < 9; ++i)
            result += n_g(i)*pow(tau, J_g(i));
 
        // residual part
        for (int i = 0; i < 43; ++i)
            result += n_r(i)*
                      pow(pi, I_r(i))*
                      pow(tau - 0.5, J_r(i));
        return result;
    }
 
    static Scalar dGamma_dTau(Scalar temperature, Scalar pressure)
    {
        Scalar tau_ = tau(temperature);   /* reduced temperature */
        Scalar pi_ = pi(pressure);    /* reduced pressure */
 
        // ideal gas part
        using std::pow;
        Scalar result = 0;
        for (int i = 0; i < 9; i++) {
            result += n_g(i) *
                      J_g(i) *
                      pow(tau_, J_g(i) - 1);
        }
 
        // residual part
        for (int i = 0; i < 43; i++) {
            result += n_r(i) *
                      pow(pi_,  I_r(i)) *
                      J_r(i) *
                      pow(tau_ - 0.5, J_r(i) - 1);
        }
 
        return result;
    }
 
    static Scalar dGamma_dPi(Scalar temperature, Scalar pressure)
    {
        Scalar tau_ = tau(temperature);   /* reduced temperature */
        Scalar pi_ = pi(pressure);    /* reduced pressure */
 
        // ideal gas part
        Scalar result = 1/pi_;
 
        // residual part
        using std::pow;
        for (int i = 0; i < 43; i++) {
            result += n_r(i) *
                      I_r(i) *
                      pow(pi_, I_r(i) - 1) *
                      pow(tau_ - 0.5, J_r(i));
        }
 
        return result;
    }
 
    static Scalar ddGamma_dTaudPi(Scalar temperature, Scalar pressure)
    {
        Scalar tau_ = tau(temperature);   /* reduced temperature */
        Scalar pi_ = pi(pressure);    /* reduced pressure */
 
        // ideal gas part
        Scalar result = 0;
 
        // residual part
        using std::pow;
        for (int i = 0; i < 43; i++) {
            result += n_r(i) *
                      I_r(i) *
                      J_r(i) *
                      pow(pi_, I_r(i) - 1) *
                      pow(tau_ - 0.5, J_r(i) - 1);
        }
 
        return result;
    }
 
    static Scalar ddGamma_ddPi(Scalar temperature, Scalar pressure)
    {
        Scalar tau_ = tau(temperature);   /* reduced temperature */
        Scalar pi_ = pi(pressure);    /* reduced pressure */
 
        // ideal gas part
        Scalar result = -1/(pi_*pi_);
 
        // residual part
        using std::pow;
        for (int i = 0; i < 43; i++) {
            result += n_r(i) *
                      I_r(i) *
                      (I_r(i) - 1) *
                      pow(pi_, I_r(i) - 2) *
                      pow(tau_ - 0.5, J_r(i));
        }
 
        return result;
    }
 
    static Scalar ddGamma_ddTau(Scalar temperature, Scalar pressure)
    {
        Scalar tau_ = tau(temperature);   /* reduced temperature */
        Scalar pi_ = pi(pressure);    /* reduced pressure */
 
        // ideal gas part
        using std::pow;
        Scalar result = 0;
        for (int i = 0; i < 9; i++) {
            result += n_g(i) *
                      J_g(i) *
                      (J_g(i) - 1) *
                      pow(tau_, J_g(i) - 2);
        }
 
        // residual part
        using std::pow;
        for (int i = 0; i < 43; i++) {
            result += n_r(i) *
                      pow(pi_,  I_r(i)) *
                      J_r(i) *
                      (J_r(i) - 1.) *
                      pow(tau_ - 0.5, J_r(i) - 2.);
        }
 
        return result;
    }
 
private:
    static Scalar n_g(int i)
    {
        constexpr const Scalar n[9] = {
            -0.96927686500217e1, 0.10086655968018e2, -0.56087911283020e-2,
            0.71452738081455e-1, -0.40710498223928, 0.14240819171444e1,
            -0.43839511319450e1, -0.28408632460772, 0.21268463753307e-1
        };
        return n[i];
    }
 
    static Scalar n_r(int i)
    {
        constexpr const Scalar n[43] = {
            -0.17731742473213e-2, -0.17834862292358e-1, -0.45996013696365e-1,
            -0.57581259083432e-1, -0.50325278727930e-1, -0.33032641670203e-4,
            -0.18948987516315e-3, -0.39392777243355e-2, -0.43797295650573e-1,
            -0.26674547914087e-4, 0.20481737692309e-7, 0.43870667284435e-6,
            -0.32277677238570e-4, -0.15033924542148e-2, -0.40668253562649e-1,
            -0.78847309559367e-9, 0.12790717852285e-7, 0.48225372718507e-6,
             0.22922076337661e-5, -0.16714766451061e-10, -0.21171472321355e-2,
            -0.23895741934104e2, -0.59059564324270e-17, -0.12621808899101e-5,
            -0.38946842435739e-1, 0.11256211360459e-10, -0.82311340897998e1,
             0.19809712802088e-7, 0.10406965210174e-18, -0.10234747095929e-12,
            -0.10018179379511e-8, -0.80882908646985e-10, 0.10693031879409,
            -0.33662250574171, 0.89185845355421e-24, 0.30629316876232e-12,
            -0.42002467698208e-5, -0.59056029685639e-25, 0.37826947613457e-5,
            -0.12768608934681e-14, 0.73087610595061e-28, 0.55414715350778e-16,
            -0.94369707241210e-6
        };
        return n[i];
    }
 
    static Scalar I_r(int i)
    {
        constexpr const short int I[43] = {
            1, 1, 1,
            1, 1, 2,
            2, 2, 2,
            2, 3, 3,
            3, 3, 3,
            4, 4, 4,
            5, 6, 6,
            6, 7, 7,
            7, 8, 8,
            9, 10, 10,
            10, 16, 16,
            18, 20, 20,
            20, 21, 22,
            23, 24, 24,
            24
        };
        return I[i];
    }
 
    static Scalar J_g(int i)
    {
        constexpr const short int J[9] = {
            0, 1, -5,
            -4, -3, -2,
            -1, 2, 3
        };
        return J[i];
    }
 
    static Scalar J_r(int i)
    {
        constexpr const short int J[43] = {
            0, 1, 2,
            3, 6, 1,
            2, 4, 7,
            36, 0, 1,
            3, 6, 35,
            1, 2, 3,
            7, 3, 16,
            35, 0, 11,
            25, 8, 36,
            13, 4, 10,
            14, 29, 50,
            57, 20, 35,
            48, 21, 53,
            39, 26, 40,
            58
        };
        return J[i];
    }
 
};
 
} // end namespace IAPWS
} // end namespace Dumux
 
#endif